Preparation and electrochemical characterization of magnesium gel electrolytes based on crosslinked Poly(tetrahydrofuran)

نویسندگان

چکیده

A crosslinked poly(tetrahydrofuran) (c-PTHF) was synthesized as a novel polymer matrix for gel electrolyte (GPE) swelled with Mg(TFSI)2/triglyme solution to develop Mg-ion battery. Two GPE based on c-PTHF different crosslinking structure and crosslinker ratio were obtained free-standing membranes excellent heat resistance. From the CV measurement, Pt/GPE/AZ31 cell clearly showed Mg redox reaction, values of current densities in reduction/oxidation peaks Coulombic efficiency larger than those triglyme solution. This may be due changes solvation Mg2+ ions by presence structures network framework.

برای دانلود باید عضویت طلایی داشته باشید

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

Electrochemical Preparation and Characterization of Mn5O8 Nanostructures

Electrochemical synthesis followed by heat-treatment is a facile and easy method for preparation of nanostructured metal oxides. Herein we report nanostructured Mn5O8 prepared through pulse cathodic deposition followed by heat-treatment for the first time. For the preparation of Mn5O8 nanorods, pulse cathodic electrodeposition was first done from 0.005M Mn(NO3)2 at the current density of 5 mA c...

متن کامل

Formulation and characterization of alprazolam transdermal gel based on nanoliposomes

Background: Nowadays transdermal drug delivery systems (TDDS), as an appropriate replacement for oral and parenteral dosage forms, are developing. These systems which designed to transport drugs through skin layers into the systemic circulation, have several benefits such as avoiding first-pass metabolism, sustained and controlled drug release, reducing side effects, and ease of use. The aim of...

متن کامل

Preparation and Characterization of Reduced Graphene Oxide Doped in Sol-Gel Derived Silica for Application in Electrochemical Double-Layer Capacitors

In this study, a new graphene ceramic composite (GCC) was prepared based on the reduced grapheneoxide (rGO) doped in sol-gel derived silica. The GCC was prepared by dispersing rGO nanosheets intothe sol-gel precursors containing methyl triethoxysilane, methanol and hydrochloric acid solution.During an acid catalyzed hydrolyze reaction and gelation proc...

متن کامل

the effect of oxytetracycline on serum calcium, phosphorus and magnesium in cattle

نتایج این مطالعه نشان می دهد که مقدار کلسیم (یونیزه و تام)، منیزیم و فسفر به طور معنی داری تغییر پیدا کرد به جزء مقدار کلسیم تام و منیزیم در روش داخل عضلانی که تغییر معنی داری نداشته است. بر اساس نتایج این مطالعه می توان نتیجه گیری کرد که اکسی تتراساکلین بر روی مقادیر سرمی کلسیم و منیزیم تأثیر می گذارد باید مقدار این کاتیون ها در بیماران، در هنگامی که اکسی تتراسایکلین استفاده می شود مورد توجه ق...

15 صفحه اول

Synthesis and Characterization of Cellulose-Based Hydrogels to Be Used as Gel Electrolytes

Cellulose-based hydrogels, obtained by tuned, low-cost synthetic routes, are proposed as convenient gel electrolyte membranes. Hydrogels have been prepared from different types of cellulose by optimized solubilization and crosslinking steps. The obtained gel membranes have been characterized by infrared spectroscopy, scanning electron microscopy, thermogravimetric analysis, and mechanical tests...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

ژورنال

عنوان ژورنال: Polymer

سال: 2021

ISSN: ['1873-2291', '0032-3861']

DOI: https://doi.org/10.1016/j.polymer.2021.123743